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mBr-phenide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C6H4Br- + Hydrogen cation = Benzene, bromo-

By formula: C6H4Br- + H+ = C6H5Br

Quantity Value Units Method Reference Comment
Deltar1605. ± 8.8kJ/molBranWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes
Quantity Value Units Method Reference Comment
Deltar1570. ± 9.2kJ/molH-TSWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C6H4Br- + Hydrogen cation = Benzene, bromo-

By formula: C6H4Br- + H+ = C6H5Br

Quantity Value Units Method Reference Comment
Deltar1605. ± 8.8kJ/molBranWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes
Quantity Value Units Method Reference Comment
Deltar1570. ± 9.2kJ/molH-TSWenthold and Squires, 1995gas phase; By HO- cleavage of substituted silanes

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wenthold and Squires, 1995
Wenthold, P.G.; Squires, R.R., Determination of the gas-phase acidities of halogen-substituted aromatic compounds using the silane-cleavage method, J. Mass Spectrom., 1995, 30, 1, 17, https://doi.org/10.1002/jms.1190300105 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References