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MeGeH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH5Ge- + Hydrogen cation = CH6Ge

By formula: CH5Ge- + H+ = CH6Ge

Quantity Value Units Method Reference Comment
Deltar1537. ± 8.8kJ/molG+TSDecouzon, Gal, et al., 1993gas phase
Deltar1534. ± 8.8kJ/molG+TSGal, Decouzon, et al., 2001gas phase
Quantity Value Units Method Reference Comment
Deltar1503. ± 8.4kJ/molIMREDecouzon, Gal, et al., 1993gas phase
Deltar1501. ± 8.4kJ/molIMREGal, Decouzon, et al., 2001gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

CH5Ge- + Hydrogen cation = CH6Ge

By formula: CH5Ge- + H+ = CH6Ge

Quantity Value Units Method Reference Comment
Deltar1537. ± 8.8kJ/molG+TSDecouzon, Gal, et al., 1993gas phase
Deltar1534. ± 8.8kJ/molG+TSGal, Decouzon, et al., 2001gas phase
Quantity Value Units Method Reference Comment
Deltar1503. ± 8.4kJ/molIMREDecouzon, Gal, et al., 1993gas phase
Deltar1501. ± 8.4kJ/molIMREGal, Decouzon, et al., 2001gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Decouzon, Gal, et al., 1993
Decouzon, M.; Gal, J.F.; Gayraud, J.; Maria, P.C.; Vaglio, G.A.; Volpe, P., Fourier Transform-Ion Cyclotron Resonance Study of the Gas-Phase Acidities of Germane and Methylgermane - Bond Dissociation Energy of German, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 54, https://doi.org/10.1016/1044-0305(93)85042-V . [all data]

Gal, Decouzon, et al., 2001
Gal, J.F.; Decouzon, M.; Maria, P.C.; Gonzalez, A.I.; Mo, O.; Yanez, M.; El Chaouch, S.; Guillemin, J.C., Acidity trends in alpha,beta-unsaturated alkanes, silanes, germanes, and stannanes, J. Am. Chem. Soc., 2001, 123, 26, 6353-6359, https://doi.org/10.1021/ja004079j . [all data]


Notes

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