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Me3Ge anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H9Ge- + Hydrogen cation = C3H10Ge

By formula: C3H9Ge- + H+ = C3H10Ge

Quantity Value Units Method Reference Comment
Deltar1543. ± 8.8kJ/molD-EABrinkman, Salomon, et al., 1995gas phase; D-EA cycle implies BDE(Me3Ge-H) = 80.2
Deltar1514. ± 13.kJ/molG+TSBrinkman, Salomon, et al., 1995gas phase; Acidity between mF- and oF-aniline.
Quantity Value Units Method Reference Comment
Deltar1512. ± 9.2kJ/molH-TSBrinkman, Salomon, et al., 1995gas phase; D-EA cycle implies BDE(Me3Ge-H) = 80.2
Deltar1484. ± 13.kJ/molIMRBBrinkman, Salomon, et al., 1995gas phase; Acidity between mF- and oF-aniline.

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brinkman, Salomon, et al., 1995
Brinkman, E.A.; Salomon, K.; Tumas, W.; Brauman, J.I., Electron affinities and gas-phase acidities of organogermanium and organotin compounds, J. Am. Chem. Soc., 1995, 117, 17, 4905, https://doi.org/10.1021/ja00122a022 . [all data]


Notes

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