(O2N)2N anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

N3O4- + Hydrogen cation = HN3O4

By formula: N3O4- + H+ = HN3O4

Quantity Value Units Method Reference Comment
Δr307.4 ± 7.1kcal/molG+TSSchmitt, Krempp, et al., 1992gas phase; Acidity between H2SO4, HNO3..NO3-. Reported: G: 297±7 kcal/mol. Readjusted to newer acidities - JEB; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Δr300.5 ± 7.0kcal/molIMRBSchmitt, Krempp, et al., 1992gas phase; Acidity between H2SO4, HNO3..NO3-. Reported: G: 297±7 kcal/mol. Readjusted to newer acidities - JEB; value altered from reference due to change in acidity scale

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
>2.54998IMRBSchmitt, Krempp, et al., 1992No electron transfer to Cl2

Protonation reactions

N3O4- + Hydrogen cation = HN3O4

By formula: N3O4- + H+ = HN3O4

Quantity Value Units Method Reference Comment
Δr307.4 ± 7.1kcal/molG+TSSchmitt, Krempp, et al., 1992gas phase; Acidity between H2SO4, HNO3..NO3-. Reported: G: 297±7 kcal/mol. Readjusted to newer acidities - JEB; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Δr300.5 ± 7.0kcal/molIMRBSchmitt, Krempp, et al., 1992gas phase; Acidity between H2SO4, HNO3..NO3-. Reported: G: 297±7 kcal/mol. Readjusted to newer acidities - JEB; value altered from reference due to change in acidity scale

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schmitt, Krempp, et al., 1992
Schmitt, R.J.; Krempp, M.; Bierbaum, V.M., Gas Phase Chemistry of Dinitramide and Nitroacetylide Ions, Int. J. Mass Spectrom. Ion Proc., 1992, 117, 621, https://doi.org/10.1016/0168-1176(92)80116-I . [all data]


Notes

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