CH2=CHCH(SMe) anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
1.04 ± 0.22D-EADahlke and Kass, 1991Between iPrOH, MeCN. Reprotonation site uncertain.

Protonation reactions

C4H7S- + Hydrogen cation = Sulfide, allyl methyl

By formula: C4H7S- + H+ = C4H8S

Quantity Value Units Method Reference Comment
Δr373.6 ± 4.1kcal/molG+TSDahlke and Kass, 1991gas phase; Between iPrOH, MeCN. Reprotonation site uncertain.
Quantity Value Units Method Reference Comment
Δr367.0 ± 4.0kcal/molIMRBDahlke and Kass, 1991gas phase; Between iPrOH, MeCN. Reprotonation site uncertain.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dahlke and Kass, 1991
Dahlke, G.D.; Kass, S.R., Substituent Effects in the Gas Phase - 1-Substituted Allyl Anions, J. Am. Chem. Soc., 1991, 113, 15, 5566, https://doi.org/10.1021/ja00015a008 . [all data]


Notes

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