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CH2=CHCHF anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H4F- + Hydrogen cation = Allyl fluoride

By formula: C3H4F- + H+ = C3H5F

Quantity Value Units Method Reference Comment
Deltar1628. ± 17.kJ/molG+TSDahlke and Kass, 1991gas phase; Between H2O, furan. Reprotonation site uncertain
Quantity Value Units Method Reference Comment
Deltar1598. ± 17.kJ/molIMRBDahlke and Kass, 1991gas phase; Between H2O, furan. Reprotonation site uncertain

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C3H4F- + Hydrogen cation = Allyl fluoride

By formula: C3H4F- + H+ = C3H5F

Quantity Value Units Method Reference Comment
Deltar1628. ± 17.kJ/molG+TSDahlke and Kass, 1991gas phase; Between H2O, furan. Reprotonation site uncertain
Quantity Value Units Method Reference Comment
Deltar1598. ± 17.kJ/molIMRBDahlke and Kass, 1991gas phase; Between H2O, furan. Reprotonation site uncertain

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dahlke and Kass, 1991
Dahlke, G.D.; Kass, S.R., Substituent Effects in the Gas Phase - 1-Substituted Allyl Anions, J. Am. Chem. Soc., 1991, 113, 15, 5566, https://doi.org/10.1021/ja00015a008 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References