(CO)3Fe-butadienide anion
- Formula: C7H5FeO3-
- Molecular weight: 192.958
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
C7H5FeO3- + =
By formula: C7H5FeO3- + H+ = C7H6FeO3
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrG° | 340.0 ± 5.0 | kcal/mol | IMRB | Wang and Squires, 1987 | gas phase; Butadiene-Fe(CO)3 deprotonated by PhO-, not by N3- |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
C7H5FeO3- + =
By formula: C7H5FeO3- + H+ = C7H6FeO3
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrG° | 340.0 ± 5.0 | kcal/mol | IMRB | Wang and Squires, 1987 | gas phase; Butadiene-Fe(CO)3 deprotonated by PhO-, not by N3- |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wang and Squires, 1987
Wang, D.N.; Squires, R.R.,
Gas Phase Ion Chemistry of Two Isomeric (C4H6)Fe(CO)3 Complexes,
Organomet., 1987, 6, 5, 905, https://doi.org/10.1021/om00148a001
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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