HN=C(Me)S anion
- Formula: C2H4NS-
- Molecular weight: 74.125
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 2.52 ± 0.13 | D-EA | Decouzon, Exner, et al., 1994 |
Protonation reactions
C2H4NS- + =
By formula: C2H4NS- + H+ = C2H5NS
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 346.4 ± 2.1 | kcal/mol | G+TS | Decouzon, Exner, et al., 1994 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 339.4 ± 2.0 | kcal/mol | IMRE | Decouzon, Exner, et al., 1994 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Decouzon, Exner, et al., 1994
Decouzon, M.; Exner, O.; Gal, J.F.; Maria, P.C.; Waisser, K.,
Acidity and basicity of thiocarboxamides in the gas phase,
J. Phys. Org. Chem., 1994, 7, 9, 511, https://doi.org/10.1002/poc.610070907
. [all data]
Notes
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- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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