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NCCH=C(OEt)O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C5H6NO2- + Hydrogen cation = Ethyl cyanoacetate

By formula: C5H6NO2- + H+ = C5H7NO2

Quantity Value Units Method Reference Comment
Deltar1422. ± 9.6kJ/molG+TSTaft and Bordwell, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar1396. ± 8.4kJ/molIMRETaft and Bordwell, 1988gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.85 ± 0.13D-EATaft and Bordwell, 1988 

Protonation reactions

C5H6NO2- + Hydrogen cation = Ethyl cyanoacetate

By formula: C5H6NO2- + H+ = C5H7NO2

Quantity Value Units Method Reference Comment
Deltar1422. ± 9.6kJ/molG+TSTaft and Bordwell, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar1396. ± 8.4kJ/molIMRETaft and Bordwell, 1988gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taft and Bordwell, 1988
Taft, R.W.; Bordwell, F.G., Structural and Solvent Effects Evaluated from Acidities Measured in Dimethyl Sulfoxide and in the Gas Phase, Acc. Chem. Res., 1988, 21, 12, 463, https://doi.org/10.1021/ar00156a005 . [all data]


Notes

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