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cPr-C(=O)-cyclopropanide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C7H9O- + Hydrogen cation = Methanone, dicyclopropyl-

By formula: C7H9O- + H+ = C7H10O

Quantity Value Units Method Reference Comment
Deltar375.1 ± 4.1kcal/molG+TSBrickhouse and Squires, 1988gas phase; Between EtOH, EtOAc
Quantity Value Units Method Reference Comment
Deltar368.0 ± 4.0kcal/molIMRBBrickhouse and Squires, 1988gas phase; Between EtOH, EtOAc

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C7H9O- + Hydrogen cation = Methanone, dicyclopropyl-

By formula: C7H9O- + H+ = C7H10O

Quantity Value Units Method Reference Comment
Deltar375.1 ± 4.1kcal/molG+TSBrickhouse and Squires, 1988gas phase; Between EtOH, EtOAc
Quantity Value Units Method Reference Comment
Deltar368.0 ± 4.0kcal/molIMRBBrickhouse and Squires, 1988gas phase; Between EtOH, EtOAc

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brickhouse and Squires, 1988
Brickhouse, M.D.; Squires, R.R., Gas Phase Bronsted vs. Lewis Acid-Base Reactions of 6,6-Dimethylfulvene. A Sensitive Probe of the Electronic Structures of Organic Anions, J. Am. Chem. Soc., 1988, 110, 9, 2706, https://doi.org/10.1021/ja00217a002 . [all data]


Notes

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