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PhCH(Me)O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C8H9O- + Hydrogen cation = Benzenemethanol, α-methyl-

By formula: C8H9O- + H+ = C8H10O

Quantity Value Units Method Reference Comment
Deltar368.1 ± 2.5kcal/molG+TSAbboud, Koppel, et al., 2013gas phase
Quantity Value Units Method Reference Comment
Deltar361.5 ± 2.4kcal/molIMREAbboud, Koppel, et al., 2013gas phase
Deltar361.3 ± 2.8kcal/molCIDCGraul, Schnute, et al., 1990gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.15 ± 0.14D-EAAbboud, Koppel, et al., 2013 

Protonation reactions

C8H9O- + Hydrogen cation = Benzenemethanol, α-methyl-

By formula: C8H9O- + H+ = C8H10O

Quantity Value Units Method Reference Comment
Deltar368.1 ± 2.5kcal/molG+TSAbboud, Koppel, et al., 2013gas phase
Quantity Value Units Method Reference Comment
Deltar361.5 ± 2.4kcal/molIMREAbboud, Koppel, et al., 2013gas phase
Deltar361.3 ± 2.8kcal/molCIDCGraul, Schnute, et al., 1990gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Abboud, Koppel, et al., 2013
Abboud, J.L.M.; Koppel, I.A.; Koppel, I., Additivity of substituent effects on the acidity of alcohols, J. Phys. Org. Chem., 2013, 26, 6, 467-472, https://doi.org/10.1002/poc.3110 . [all data]

Graul, Schnute, et al., 1990
Graul, S.T.; Schnute, M.E.; Squires, R.R., Gas-Phase Acidities of Carboxylic Acids and Alcohols from Collision-Induced Dissociation of Dimer Cluster Ions, Int. J. Mass Spectrom. Ion Proc., 1990, 96, 2, 181, https://doi.org/10.1016/0168-1176(90)87028-F . [all data]


Notes

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