MeOSO2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH3O3S- + Hydrogen cation = CH4O3S

By formula: CH3O3S- + H+ = CH4O3S

Quantity Value Units Method Reference Comment
Δr344.0 ± 5.1kcal/molG+TSGrabowski and Lum, 1990gas phase; Comparable to MeCOCH2COMe; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Δr336.6 ± 5.0kcal/molIMRBGrabowski and Lum, 1990gas phase; Comparable to MeCOCH2COMe; value altered from reference due to change in acidity scale

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Grabowski and Lum, 1990
Grabowski, J.J.; Lum, R.C., Selectivity as a Function of Anionic Base Properties in the Gas Phase Reactions of Dimethyl Sulfite, J. Am. Chem. Soc., 1990, 112, 2, 607, https://doi.org/10.1021/ja00158a018 . [all data]


Notes

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