MeSiH2CH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H7Si- + Hydrogen cation = Silane, dimethyl-

By formula: C2H7Si- + H+ = C2H8Si

Quantity Value Units Method Reference Comment
Δr1643. ± 26.kJ/molG+TSDamrauer, Kass, et al., 1988gas phase; Between Me2NH and fluorobenzene
Quantity Value Units Method Reference Comment
Δr1607. ± 25.kJ/molIMRBDamrauer, Kass, et al., 1988gas phase; Between Me2NH and fluorobenzene

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C2H7Si- + Hydrogen cation = Silane, dimethyl-

By formula: C2H7Si- + H+ = C2H8Si

Quantity Value Units Method Reference Comment
Δr1643. ± 26.kJ/molG+TSDamrauer, Kass, et al., 1988gas phase; Between Me2NH and fluorobenzene
Quantity Value Units Method Reference Comment
Δr1607. ± 25.kJ/molIMRBDamrauer, Kass, et al., 1988gas phase; Between Me2NH and fluorobenzene

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, Kass, et al., 1988
Damrauer, R.; Kass, S.R.; DePuy, C.H., Gas-Phase Acidities of Methylsilanes: C-H versus Si-H, Organomet., 1988, 7, 3, 637, https://doi.org/10.1021/om00093a011 . [all data]


Notes

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