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IBr2 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-60.00kcal/molLattFinch, Gates, et al., 1977Structure appears to be BrIBr-: Sanov, Sanford, et al., 1999

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Br2I- + iodine bromide = (Br2I- bullet iodine bromide)

By formula: Br2I- + BrI = (Br2I- bullet BrI)

Quantity Value Units Method Reference Comment
Deltar19.90kcal/molTherFinch, Gates, et al., 1977gas phase; Structure appears to be BrIBr-: Sanov, Sanford, et al., 1999
Deltar38.20kcal/molN/ACheck, Faust, et al., 2001gas phase; FeF4-; ; «DELTA»S(EA)=5.7
Quantity Value Units Method Reference Comment
Deltar27.30kcal/molN/ACheck, Faust, et al., 2001gas phase; FeF4-; ; «DELTA»S(EA)=5.7

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Finch, Gates, et al., 1977
Finch, A.; Gates, P.N.; Peake, S.J., Thermochemistry of polyhalides. III. Cesium and rubidium tetrachloroiodates, J. Inorg. Nucl. Chem., 1977, 39, 2135. [all data]

Sanov, Sanford, et al., 1999
Sanov, A.; Sanford, T.; Butler, L.J.; Vala, J.; Kosloff, R.; Lineberger, W.C., Photodissociation dynamics of gas-phase BrICl- and IBr2- anions, J. Phys. Chem. A, 1999, 103, 49, 10244-10254, https://doi.org/10.1021/jp9920803 . [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References