MeC(=NOMe)CH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C4H8NO- + Hydrogen cation = 2-Propanone, O-methyloxime

By formula: C4H8NO- + H+ = C4H9NO

Quantity Value Units Method Reference Comment
Δr372.8 ± 4.0kcal/molN/AHair, Carrigan, et al., 1989gas phase; Acidity near DMSO.
Quantity Value Units Method Reference Comment
Δr365.7 ± 3.5kcal/molIMRBHair, Carrigan, et al., 1989gas phase; Acidity near DMSO.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
<1.10999IMRBHair, Carrigan, et al., 1989Transfers electron to SO2

Protonation reactions

C4H8NO- + Hydrogen cation = 2-Propanone, O-methyloxime

By formula: C4H8NO- + H+ = C4H9NO

Quantity Value Units Method Reference Comment
Δr372.8 ± 4.0kcal/molN/AHair, Carrigan, et al., 1989gas phase; Acidity near DMSO.
Quantity Value Units Method Reference Comment
Δr365.7 ± 3.5kcal/molIMRBHair, Carrigan, et al., 1989gas phase; Acidity near DMSO.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hair, Carrigan, et al., 1989
Hair, O.; Carrigan, K.E.; Bierbaum, V.M.; DePuy, C.H., Gas Phase Ion Chemistry of Nitrogen Containing Negative Ions: Deprotonated Nitromethane, Acetone Oxime, and Acetone Oxime O-methyl Ether, Int. J. Mass Spectrom. Ion Proc., 1989, 90, 3, 295, https://doi.org/10.1016/0168-1176(89)80074-6 . [all data]


Notes

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