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tBuCH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C5H11- + Hydrogen cation = Neopentane

By formula: C5H11- + H+ = C5H12

Quantity Value Units Method Reference Comment
Deltar408.9 ± 2.0kcal/molBranDePuy, Gronert, et al., 1989gas phase
Deltar411. ± 10.kcal/molCIDTGraul and Squires, 1990gas phase
Quantity Value Units Method Reference Comment
Deltar400.1 ± 2.1kcal/molH-TSDePuy, Gronert, et al., 1989gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C5H11- + Hydrogen cation = Neopentane

By formula: C5H11- + H+ = C5H12

Quantity Value Units Method Reference Comment
Deltar408.9 ± 2.0kcal/molBranDePuy, Gronert, et al., 1989gas phase
Deltar411. ± 10.kcal/molCIDTGraul and Squires, 1990gas phase
Quantity Value Units Method Reference Comment
Deltar400.1 ± 2.1kcal/molH-TSDePuy, Gronert, et al., 1989gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DePuy, Gronert, et al., 1989
DePuy, C.H.; Gronert, S.; Barlow, S.E.; Bierbaum, V.M.; Damrauer, R., The Gas Phase Acidities of the Alkanes, J. Am. Chem. Soc., 1989, 111, 6, 1968, https://doi.org/10.1021/ja00188a003 . [all data]

Graul and Squires, 1990
Graul, S.T.; Squires, R.R., Gas-Phase Acidities Derived from Threshold Energies for Activated Reactions, J. Am. Chem. Soc., 1990, 112, 7, 2517, https://doi.org/10.1021/ja00163a007 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References