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iPrCH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C4H9- + Hydrogen cation = Isobutane

By formula: C4H9- + H+ = C4H10

Quantity Value Units Method Reference Comment
Deltar1728. ± 8.4kJ/molBranDePuy, Gronert, et al., 1989gas phase
Deltar1735. ± 20.kJ/molBranPeerboom, Rademaker, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Deltar1692. ± 8.8kJ/molH-TSDePuy, Gronert, et al., 1989gas phase
Deltar1699. ± 21.kJ/molH-TSPeerboom, Rademaker, et al., 1992gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C4H9- + Hydrogen cation = Isobutane

By formula: C4H9- + H+ = C4H10

Quantity Value Units Method Reference Comment
Deltar1728. ± 8.4kJ/molBranDePuy, Gronert, et al., 1989gas phase
Deltar1735. ± 20.kJ/molBranPeerboom, Rademaker, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Deltar1692. ± 8.8kJ/molH-TSDePuy, Gronert, et al., 1989gas phase
Deltar1699. ± 21.kJ/molH-TSPeerboom, Rademaker, et al., 1992gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DePuy, Gronert, et al., 1989
DePuy, C.H.; Gronert, S.; Barlow, S.E.; Bierbaum, V.M.; Damrauer, R., The Gas Phase Acidities of the Alkanes, J. Am. Chem. Soc., 1989, 111, 6, 1968, https://doi.org/10.1021/ja00188a003 . [all data]

Peerboom, Rademaker, et al., 1992
Peerboom, R.A.L.; Rademaker, G.J.; Dekoning, L.J.; Nibbering, N.M.M., Stabilization of Cycloalkyl Carbanions in the Gas Phase, Rapid Commun. Mass Spectrom., 1992, 6, 6, 394, https://doi.org/10.1002/rcm.1290060608 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References