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bicyclo[1.1.0]butanide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C4H5- + Hydrogen cation = Bicyclo[1.1.0]butane

By formula: C4H5- + H+ = C4H6

Quantity Value Units Method Reference Comment
Deltar1670. ± 17.kJ/molG+TSKass and Chou, 1988gas phase; Acidity between NH3, Me2NH, near nPrNH2.
Quantity Value Units Method Reference Comment
Deltar1636. ± 17.kJ/molIMRBKass and Chou, 1988gas phase; Acidity between NH3, Me2NH, near nPrNH2.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kass and Chou, 1988
Kass, S.R.; Chou, P.K., The Bicyclobutyl Anion: An Alkyl Carbanion, J. Am. Chem. Soc., 1988, 110, 23, 7899, https://doi.org/10.1021/ja00231a063 . [all data]


Notes

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