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Cl3 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-326.5kJ/molTherNizzi, Pommerening, et al., 1998 
Deltafgas-300.4kJ/molIMRERobbiani and Franklin, 1979«DELTA»G~=+1 kcal for Cl- + SO2Cl2 <=> Cl3- + SO2
Deltafgas-300. ± 21.kJ/molIMRBRobbiani and Franklin, 1979, 2 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Chlorine = Cl3-

By formula: Cl- + Cl2 = Cl3-

Quantity Value Units Method Reference Comment
Deltar99.2 ± 5.0kJ/molCIDTNizzi, Pommerening, et al., 1998gas phase
Deltar69.87kJ/molTherRobbiani and Franklin, 1979gas phase; «DELTA»G~=+1 kcal for Cl- + SO2Cl2 <=> Cl3- + SO2
Deltar<182.4kJ/molPDisLee, Smith, et al., 1979gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
<4.640 ± 0.010LPESKaledin, Heaven, et al., 1999 
5.10 ± 0.20NBAEBowen, Liesegang, et al., 1983 
>4.30 ± 0.22R-ARobbiani and Franklin, 1979, 2 

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Chlorine = Cl3-

By formula: Cl- + Cl2 = Cl3-

Quantity Value Units Method Reference Comment
Deltar99.2 ± 5.0kJ/molCIDTNizzi, Pommerening, et al., 1998gas phase
Deltar69.87kJ/molTherRobbiani and Franklin, 1979gas phase; «DELTA»G~=+1 kcal for Cl- + SO2Cl2 <=> Cl3- + SO2
Deltar<182.4kJ/molPDisLee, Smith, et al., 1979gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nizzi, Pommerening, et al., 1998
Nizzi, K.E.; Pommerening, C.A.; Sunderlin, L.S., Gas-phase thermochemistry of polyhalide anions, J. Phys. Chem. A, 1998, 102, 39, 7674-7679, https://doi.org/10.1021/jp9824508 . [all data]

Robbiani and Franklin, 1979
Robbiani, R.; Franklin, J.L., Formation of the trihalide ion Cl3- in the gas phase, J. Am. Chem. Soc., 1979, 101, 764. [all data]

Robbiani and Franklin, 1979, 2
Robbiani, R.; Franklin, J.L., Negative ion-molecule reaction in sulfuryl halides, J. Am. Chem. Soc., 1979, 101, 3709. [all data]

Lee, Smith, et al., 1979
Lee, L.C.; Smith, G.P.; Moseley, J.T.; Cosby, P.C.; Guest, J.A., Photodissociation and photodetachment of Cl2-, ClO-, Cl3-, and BrCl2-, J. Chem. Phys., 1979, 70, 3237. [all data]

Kaledin, Heaven, et al., 1999
Kaledin, A.L.; Heaven, M.C.; Morokuma, K.; Neumark, D.M., Cl-3(-) electron photodetachment spectrum: measurement and assignment, Chem. Phys. Lett., 1999, 306, 1-2, 48-52, https://doi.org/10.1016/S0009-2614(99)00419-4 . [all data]

Bowen, Liesegang, et al., 1983
Bowen, K.H.; Liesegang, G.W.; Sanders, R.A.; Herschbach, D.W., Electron Attachment to Molecular Clusters by Collisional Charge Transfer, J. Phys. Chem., 1983, 87, 4, 557-565, https://doi.org/10.1021/j100227a009 . [all data]


Notes

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