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AlF4 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-463.4 ± 2.4kcal/molTherNikitin, Igolkina, et al., 1986Summary of literature data plus new work. Recommended average value at 0K.; value altered from reference due to conversion from electron convention to ion convention
Deltafgas-500.0 ± 3.0kcal/molTDEqSrivastava, Uy, et al., 19742 AlF2 + AlF2- <=> 2AlF + AlF4-

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

AlF4- + AlF4Na = (AlF4- bullet AlF4Na)

By formula: AlF4- + AlF4Na = (AlF4- bullet AlF4Na)

Quantity Value Units Method Reference Comment
Deltar39.6 ± 2.2kcal/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention
Quantity Value Units Method Reference Comment
Deltar33.6 ± 3.2kcal/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + AlF4K = (AlF4- bullet AlF4K)

By formula: AlF4- + AlF4K = (AlF4- bullet AlF4K)

Quantity Value Units Method Reference Comment
Deltar35.1 ± 1.5kcal/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention
Quantity Value Units Method Reference Comment
Deltar29.5 ± 2.5kcal/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + Aluminum fluoride = (AlF4- bullet Aluminum fluoride)

By formula: AlF4- + AlF3 = (AlF4- bullet AlF3)

Quantity Value Units Method Reference Comment
Deltar48.8 ± 1.0kcal/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention
Quantity Value Units Method Reference Comment
Deltar41.8 ± 2.0kcal/molTDAsSidorov, Nikitin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + cobalt trifluoride = (AlF4- bullet cobalt trifluoride)

By formula: AlF4- + CoF3 = (AlF4- bullet CoF3)

Quantity Value Units Method Reference Comment
Deltar55. ± 12.kcal/molTherSidorov, Nikulin, et al., 1987gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + BeF3K = (AlF4- bullet BeF3K)

By formula: AlF4- + BeF3K = (AlF4- bullet BeF3K)

Quantity Value Units Method Reference Comment
Deltar45.8 ± 2.0kcal/molTDAsNikitin, Sorokin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + BeF3Na = (AlF4- bullet BeF3Na)

By formula: AlF4- + BeF3Na = (AlF4- bullet BeF3Na)

Quantity Value Units Method Reference Comment
Deltar45.9 ± 2.0kcal/molTDAsNikitin, Sorokin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + F3Ga = (AlF4- bullet F3Ga)

By formula: AlF4- + F3Ga = (AlF4- bullet F3Ga)

Quantity Value Units Method Reference Comment
Deltar48.3 ± 4.2kcal/molTDEqZhuravleva, Nikitin, et al., 1985gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + Potassium fluoride = (AlF4- bullet Potassium fluoride)

By formula: AlF4- + FK = (AlF4- bullet FK)

Quantity Value Units Method Reference Comment
Deltar28.6 ± 2.0kcal/molTDAsGusarov, Gorokhov, et al., 1979gas phase; value altered from reference due to conversion from electron convention to ion convention

AlF4- + BeF2 = (AlF4- bullet BeF2)

By formula: AlF4- + BeF2 = (AlF4- bullet BeF2)

Quantity Value Units Method Reference Comment
Deltar43.5 ± 2.5kcal/molTDAsNikitin, Sorokin, et al., 1980gas phase; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nikitin, Igolkina, et al., 1986
Nikitin, M.I.; Igolkina, N.A.; Skokan, E.V.; Sorokin, I.D.; Sidirov, L.N., Enthalpies of formation of the AlF4- ion, J. Phys. Chem., 1986, 60, 22. [all data]

Srivastava, Uy, et al., 1974
Srivastava, R.D.; Uy, O.M.; Farber, M., Experimental determination of heats of formation of negative ions and electron affinities of several boron and aluminum fluorides, J. Chem. Soc. Faraday Trans. 1, 1974, 70, 1033. [all data]

Sidorov, Nikitin, et al., 1980
Sidorov, L.N.; Nikitin, M.I.; Skokan, E.V.; Sorokin, I.D., Mass-spectrometric determination of enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. II. Heats of formation of AlF4- and KF2-, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 203. [all data]

Sidorov, Nikulin, et al., 1987
Sidorov, L.N.; Nikulin, V.V.; Chilingarov, N.S.; Korobov, M.V., The Enthalpy of Formation of the CoF4- Ion in the Gas Phase, Russ. J. Phys. Chem., 1987, 61, 555. [all data]

Nikitin, Sorokin, et al., 1980
Nikitin, M.I.; Sorokin, I.D.; Skokan, E.V.; Sidorov, L.N., Negative Ions in the Saturated Vapors of the Potassium Fluoride - Hafnium Tetrafluoride and Potassium Fluoride - Beryllium Difluoride Systems, Russ. J. Phys. Chem., 1980, 54, page]. [all data]

Zhuravleva, Nikitin, et al., 1985
Zhuravleva, L.V.; Nikitin, M.I.; Sorokin, I.D.; Sidorov, L.N., Mass Spectrometric Determination of the Enthalpies of Dissociation of Gaseous Complex Fluorides into Neutral and Charged Particles. VIII. MF-..GaF3 Systems (M=Li, Na, K, Rb, Cs), Int. J. Mass Spectrom. Ion Proc., 1985, 65, 3, 253, https://doi.org/10.1016/0168-1176(85)87002-6 . [all data]

Gusarov, Gorokhov, et al., 1979
Gusarov, A.V.; Gorokhov, L.N.; Pyatenko, A.T.; Sidorova, I.V., Negative ions in the vapors of inorganic compounds, Adv. Mass Spectrom., 1979, 8, 262. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References