LiAlF4..MnF3 anion
- Formula: AlF7LiMn-
- Molecular weight: 221.850
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -767.2 ± 5.0 | kcal/mol | Ther | Sidorov and Gubarevich, 1982 | At 1125K; value altered from reference due to conversion from electron convention to ion convention |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
By formula: F3Mn- + AlF4Li = AlF7LiMn-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 54.7 ± 2.0 | kcal/mol | TDAs | Sidorov and Gubarevich, 1982 | gas phase; At 1125K; value altered from reference due to conversion from electron convention to ion convention |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sidorov and Gubarevich, 1982
Sidorov, L.N.; Gubarevich, G.D.,
Dissociation of the Gaseous Complex Fluorides. Alkali Metal Trifluoromanganates and Tetrafluoromanganates,
Koord. Khim., 1982, 8, 12708c. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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