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Ru(Cp*)(PMe3)2(OH)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C16H34OP2Ru (solution) + Diphenylamine (solution) = C28H43NP2Ru (solution) + Water (solution)

By formula: C16H34OP2Ru (solution) + C12H11N (solution) = C28H43NP2Ru (solution) + H2O (solution)

Quantity Value Units Method Reference Comment
Deltar5.0 ± 0.4kJ/molEqSBryndza, Fong, et al., 1987solvent: Tetrahydrofuran; In a series of reactions involving similar ruthenium complexes, the reaction enthalpy was identified with the reaction Gibbs energy, since the entropy values are expected to be small Bryndza, Fong, et al., 1987. For this reaction, however a van't Hoff plot could be used. Temperature range: 293-328 K
Deltar19.7kJ/molEqSBryndza, Fong, et al., 1987solvent: Benzene; The reaction enthalpy was identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987

C16H34OP2Ru (solution) + Hydrogen (solution) = C16H34P2Ru (solution) + Water (solution)

By formula: C16H34OP2Ru (solution) + H2 (solution) = C16H34P2Ru (solution) + H2O (solution)

Quantity Value Units Method Reference Comment
Deltar-24.7 ± 3.3kJ/molEqSBryndza, Fong, et al., 1987solvent: Tetrahydrofuran; The reaction enthalpy was identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987

C27H28OP2Pt (solution) + C28H43NP2Ru (solution) = C39H37NP2Pt (solution) + C16H34OP2Ru (solution)

By formula: C27H28OP2Pt (solution) + C28H43NP2Ru (solution) = C39H37NP2Pt (solution) + C16H34OP2Ru (solution)

Quantity Value Units Method Reference Comment
Deltar-15.1kJ/molEqSBryndza, Fong, et al., 1987solvent: Tetrahydrofuran; The reaction enthalpy can be identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987

C16H34OP2Ru (solution) + Hydrogen cyanide (solution) = C17H33NP2Ru (solution) + Water (solution)

By formula: C16H34OP2Ru (solution) + CHN (solution) = C17H33NP2Ru (solution) + H2O (solution)

Quantity Value Units Method Reference Comment
Deltar<-39.3kJ/molEqSBryndza, Fong, et al., 1987solvent: Tetrahydrofuran; The reaction enthalpy was identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987

C16H34OP2Ru (solution) + Methyl Alcohol (solution) = C17H36OP2Ru (solution) + Water (solution)

By formula: C16H34OP2Ru (solution) + CH4O (solution) = C17H36OP2Ru (solution) + H2O (solution)

Quantity Value Units Method Reference Comment
Deltar0.kJ/molESTBryndza, Fong, et al., 1987solvent: Tetrahydrofuran; The reaction enthalpy was identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bryndza, Fong, et al., 1987
Bryndza, H.E.; Fong, L.K.; Paciello, R.A.; Tam, W.; Bercaw, J.E., J. Am. Chem. Soc., 1987, 109, 1444. [all data]


Notes

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