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Mn(CO)5(COPh)


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-724.7 ± 8.2kJ/molReviewMartinho SimõesThe enthalpy formation relies on -588.9 ± 7.0 kJ/mol for the enthalpy of formation of Mn(CO)5(Ph)(g)
Deltafgas-723.8 ± 5.8kJ/molReviewMartinho SimõesThe enthalpy formation relies on -385.8 ± 1.7 kJ/mol for the enthalpy of formation of MnBr2(cr) Connor, Zafarani-Moattar, et al., 1982
Deltafgas-724.3 ± 5.4kJ/molReviewMartinho SimõesSelected data. Average of the values from Connor, Zafarani-Moattar, et al., 1982

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid-847.7 ± 7.6kJ/molReviewMartinho SimõesThe enthalpy formation relies on -588.9 ± 7.0 kJ/mol for the enthalpy of formation of Mn(CO)5(Ph)(g)
Deltafsolid-846.8 ± 5.0kJ/molReviewMartinho SimõesThe enthalpy formation relies on -385.8 ± 1.7 kJ/mol for the enthalpy of formation of MnBr2(cr) Connor, Zafarani-Moattar, et al., 1982
Deltafsolid-847.3 ± 4.5kJ/molReviewMartinho SimõesSelected data. Average of the values from Connor, Zafarani-Moattar, et al., 1982

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub123. ± 3.kJ/molTD-HFCConnor, Zafarani-Moattar, et al., 1982 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C11H5MnO5 (solution) + Carbon monoxide (solution) = C12H5MnO6 (solution)

By formula: C11H5MnO5 (solution) + CO (solution) = C12H5MnO6 (solution)

Quantity Value Units Method Reference Comment
Deltar-45.2kJ/molEqSCalderazzo, 1977solvent: 2,2'-diethoxydiethyl ether

C12H5MnO6 (cr) = C11H5MnO5 (g) + Carbon monoxide (g)

By formula: C12H5MnO6 (cr) = C11H5MnO5 (g) + CO (g)

Quantity Value Units Method Reference Comment
Deltar148. ± 3.kJ/molTD-HFCConnor, Zafarani-Moattar, et al., 1982 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Calderazzo, 1977
Calderazzo, F., Angew. Chem. Int. Ed. Engl., 1977, 16, 299. [all data]


Notes

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