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W(CO)4(CPh)(Br)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C11H5IO4W (g) + Bromine (g) = C11H5BrO4W (g) + Iodine atom (g)

By formula: C11H5IO4W (g) + Br (g) = C11H5BrO4W (g) + I (g)

Quantity Value Units Method Reference Comment
Deltar-13.kcal/molEqSFischer and Seitz, 1984The reaction enthalpy relies on a single measurement of the equilibrium constant in 1,1,2-trichloroethane (at 263 K) for the reaction W(CO)4(CPh)(I)(solution) + Br(-)(solution) = W(CO)4(CPh)(Br)(solution) + I(-)(solution), and on solvation and electron affinity data. It assumes that the reaction entropy is negligible Fischer and Seitz, 1984

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fischer and Seitz, 1984
Fischer, H.; Seitz, F., J. Organometal. Chem., 1984, 268, 247. [all data]


Notes

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