W(Cp)2(I)2


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas221.6 ± 5.3kJ/molReviewMartinho Simões 
Δfgas174. ± 11.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on the enthalpy of solution of HI in toluene, -29.6 ± 2.3 kJ/mol Calado, Dias, et al., 1979, and on the enthalpy of formation of W(Cp)2(H)2(cr), 226.2 ± 8.6 kJ/mol

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid117.0 ± 3.3kJ/molReviewMartinho Simões 
Δfsolid69. ± 10.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on the enthalpy of solution of HI in toluene, -29.6 ± 2.3 kJ/mol Calado, Dias, et al., 1979, and on the enthalpy of formation of W(Cp)2(H)2(cr), 226.2 ± 8.6 kJ/mol
Quantity Value Units Method Reference Comment
Δcsolid-6324.1 ± 2.9kJ/molCC-SBTel'noi, Rabinovich, et al., 1976Please also see Tel'noi and Rabinovich, 1977.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub104.6 ± 4.2kJ/molCC-SBTel'noi, Rabinovich, et al., 1976 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Calado, Dias, et al., 1979
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V., Rev. Port. Quím., 1979, 21, 129. [all data]

Tel'noi, Rabinovich, et al., 1976
Tel'noi, V.I.; Rabinovich, I.B.; Kir'yanov, K.V.; Smirnov, A.S., Dokl. Akad. Nauk SSSR, 1976, 231, 733. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]


Notes

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