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W(Cp)2(I)2


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas221.6 ± 5.3kJ/molReviewMartinho Simões 
Deltafgas174. ± 11.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on the enthalpy of solution of HI in toluene, -29.6 ± 2.3 kJ/mol Calado, Dias, et al., 1979, and on the enthalpy of formation of W(Cp)2(H)2(cr), 226.2 ± 8.6 kJ/mol

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid117.0 ± 3.3kJ/molReviewMartinho Simões 
Deltafsolid69. ± 10.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on the enthalpy of solution of HI in toluene, -29.6 ± 2.3 kJ/mol Calado, Dias, et al., 1979, and on the enthalpy of formation of W(Cp)2(H)2(cr), 226.2 ± 8.6 kJ/mol
Quantity Value Units Method Reference Comment
Deltacsolid-6324.1 ± 2.9kJ/molCC-SBTel'noi, Rabinovich, et al., 1976Please also see Tel'noi and Rabinovich, 1977.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub104.6 ± 4.2kJ/molCC-SBTel'noi, Rabinovich, et al., 1976 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C10H12W (cr) + 2Iodine (cr) = C10H10I2W (cr) + 2Hydrogen iodide (g)

By formula: C10H12W (cr) + 2I2 (cr) = C10H10I2W (cr) + 2HI (g)

Quantity Value Units Method Reference Comment
Deltar-104.3 ± 5.5kJ/molRSCCalado, Dias, et al., 1979 

C10H11IW (cr) + Iodine (cr) = C10H10I2W (cr) + Hydrogen iodide (g)

By formula: C10H11IW (cr) + I2 (cr) = C10H10I2W (cr) + HI (g)

Quantity Value Units Method Reference Comment
Deltar-84.6 ± 4.1kJ/molRSCCalhorda, Dias, et al., 1987 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Calado, Dias, et al., 1979
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V., Rev. Port. Quím., 1979, 21, 129. [all data]

Tel'noi, Rabinovich, et al., 1976
Tel'noi, V.I.; Rabinovich, I.B.; Kir'yanov, K.V.; Smirnov, A.S., Dokl. Akad. Nauk SSSR, 1976, 231, 733. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]

Calhorda, Dias, et al., 1987
Calhorda, M.J.; Dias, A.R.; Minas da Piedade M.E.; Salema, M.S.; Martinho Simões J.A., Organometallics, 1987, 6, 734. [all data]


Notes

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