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Mo(CO)4


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-98.5 ± 6.0kcal/molReviewMartinho SimõesThe enthalpy of formation relies on -151.8 ± 3.1 kcal/mol for the enthalpy of formation of Mo(CO)5(g)
Deltafgas-91. ± 15.kcal/molReviewMartinho SimõesThe enthalpy of formation relies on -151.8 ± 3.1 kcal/mol for the enthalpy of formation of Mo(CO)5(g)
Deltafgas-95.94kcal/molReviewMartinho SimõesThe enthalpy of formation relies on -151.8 ± 3.1 kcal/mol for the enthalpy of formation of Mo(CO)5(g)

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C5MoO5 (g) = C4MoO4 (g) + Carbon monoxide (g)

By formula: C5MoO5 (g) = C4MoO4 (g) + CO (g)

Quantity Value Units Method Reference Comment
Deltar29.49kcal/molKinGRayner, Ishikawa, et al., 1991 
Deltar27.0 ± 5.0kcal/molKinGGanske and Rosenfeld, 1990 
Deltar35. ± 15.kcal/molMBPSVenkataraman, Hou, et al., 1990 

C4MoO4 (g) = C3MoO3 (g) + Carbon monoxide (g)

By formula: C4MoO4 (g) = C3MoO3 (g) + CO (g)

Quantity Value Units Method Reference Comment
Deltar31.1kcal/molKinGRayner, Ishikawa, et al., 1991 
Deltar31.1 ± 5.0kcal/molKinGGanske and Rosenfeld, 1990 
Deltar30. ± 15.kcal/molMBPSVenkataraman, Hou, et al., 1990 

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Rayner, Ishikawa, et al., 1991
Rayner, D.M.; Ishikawa, Y.; Brown, C.E.; Hackett, P.A., J. Chem. Phys., 1991, 94, 5471. [all data]

Ganske and Rosenfeld, 1990
Ganske, J.A.; Rosenfeld, R.N., J. Phys. Chem., 1990, 94, 4315. [all data]

Venkataraman, Hou, et al., 1990
Venkataraman, B.; Hou, H.; Zhang, Z.; Chen, S.; Bandukwalla, G.; Vernon, M., J. Chem. Phys., 1990, 92, 5338. [all data]


Notes

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