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Mo(Cp)2(I)2


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas131.2 ± 4.9kJ/molReviewMartinho Simões 
Deltafgas172.8 ± 9.0kJ/molReviewMartinho SimõesThe enthalpy of formation relies on the enthalpy of solution of HI in toluene, -29.6 ± 2.3 kJ/mol Calado, Dias, et al., 1979, and on the enthalpy of formation of Mo(Cp)2(H)2(cr), 213.2 ± 6.1 kJ/mol

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid30.8 ± 2.5kJ/molReviewMartinho Simões 
Deltafsolid72.4 ± 8.0kJ/molReviewMartinho SimõesThe enthalpy of formation relies on the enthalpy of solution of HI in toluene, -29.6 ± 2.3 kJ/mol Calado, Dias, et al., 1979, and on the enthalpy of formation of Mo(Cp)2(H)2(cr), 213.2 ± 6.1 kJ/mol
Quantity Value Units Method Reference Comment
Deltacsolid-6139.6 ± 2.1kJ/molCC-SBTel'noi, Rabinovich, et al., 1976Please also see Tel'noi and Rabinovich, 1977.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C10H12Mo (cr) + 2Iodine (cr) = C10H10I2Mo (cr) + 2Hydrogen iodide (g)

By formula: C10H12Mo (cr) + 2I2 (cr) = C10H10I2Mo (cr) + 2HI (g)

Quantity Value Units Method Reference Comment
Deltar-87.8 ± 5.1kJ/molRSCCalado, Dias, et al., 1979 

C12H14Mo (cr) + Iodine (cr) = C10H10I2Mo (cr) + Ethylene (g)

By formula: C12H14Mo (cr) + I2 (cr) = C10H10I2Mo (cr) + C2H4 (g)

Quantity Value Units Method Reference Comment
Deltar-163.0 ± 2.1kJ/molRSCCalhorda, Carrondo, et al., 1991 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Calado, Dias, et al., 1979
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V., Rev. Port. Quím., 1979, 21, 129. [all data]

Tel'noi, Rabinovich, et al., 1976
Tel'noi, V.I.; Rabinovich, I.B.; Kir'yanov, K.V.; Smirnov, A.S., Dokl. Akad. Nauk SSSR, 1976, 231, 733. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]

Calhorda, Carrondo, et al., 1991
Calhorda, M.J.; Carrondo, M.A.A.F.C.T.; Dias, A.R.; Galvão, A.M.; Garcia, M.H.; Martins, A.M.; Minas da Piedade, M.E.; Pinheiro, C.I.; Romão, C.C.; Martinho Simões, J.A.; Veiros, L.F., Organometallics, 1991, 10, 483. [all data]


Notes

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