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[Mo(Cp*)(CO)3]2


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

0.5C26H30Mo2O6 (solution) + sodium (cr) = C13H15MoNaO3 (solution)

By formula: 0.5C26H30Mo2O6 (solution) + Na (cr) = C13H15MoNaO3 (solution)

Quantity Value Units Method Reference Comment
Deltar-250.6 ± 6.0kJ/molRSCKiss, Nolan, et al., 1994solvent: Tetrahydrofuran; The reaction enthalpy was calculated from the enthalpies of the following reactions: 0.5[Mo(Cp*)(CO)3]2(solution) + (Na)[Cr(Cp)(CO)2(PPh3)](solution) = (Na)[Mo(Cp*)(CO)3](solution) + Cr(Cp)(CO)2(PPh3)(solution), Cr(Cp)(CO)2(PPh3)(solution) + (Na)(Ph2CO)(solution) = (Na)[Cr(Cp)(CO)2(PPh3)](solution) + Ph2CO(solution), -89.1 ± 2.5 kJ/mol, and Ph2CO(solution) + Na(cr) = (Na)(Ph2CO)(solution), -161.1 ± 2.5 kJ/mol Kiss, Nolan, et al., 1994.

C24H30Mo2O4 (solution) + 2Carbon monoxide (solution) = C26H30Mo2O6 (solution)

By formula: C24H30Mo2O4 (solution) + 2CO (solution) = C26H30Mo2O6 (solution)

Quantity Value Units Method Reference Comment
Deltar-137.6 ± 2.1kJ/molRSCNolan, López de la Vega, et al., 1986solvent: Toluene; The enthalpy of solution of [Mo(Cp*)(CO)2]2(cr) was measured as 14.6 ± 0.8 kJ/mol Nolan, López de la Vega, et al., 1986

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kiss, Nolan, et al., 1994
Kiss, G.; Nolan, S.P.; Hoff, C.D., Inorg. Chim. Acta, 1994, 227, 285. [all data]

Nolan, López de la Vega, et al., 1986
Nolan, S.P.; López de la Vega, R.; Hoff, C.D., Inorg. Chem., 1986, 25, 4446. [all data]


Notes

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