Sn(Me)3(I)
- Formula: C3H9ISn
- Molecular weight: 290.718
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -19.7 ± 1.4 | kcal/mol | Review | Martinho Simões | The enthalpy of formation relies on -18.4 ± 1.8 kcal/mol for the enthalpy of formation of Sn2(Me)6(l). |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -31.21 ± 0.98 | kcal/mol | Review | Martinho Simões | The enthalpy of formation relies on -18.4 ± 1.8 kcal/mol for the enthalpy of formation of Sn2(Me)6(l). |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔvapH° | 11.5 ± 1.0 | kcal/mol | RSC | Davies, Pope, et al., 1963 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(l) +
(cr) = 2C3H9ISn (l)
By formula: C6H18Sn2 (l) + I2 (cr) = 2C3H9ISn (l)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -44.00 ± 0.69 | kcal/mol | RSC | Pedley, Skinner, et al., 1957 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970. |
C3H9ISn (l) + (l) = (
• 55
) (solution) + C3H10OSn (cr)
By formula: C3H9ISn (l) + H2O (l) = (HI • 55H2O) (solution) + C3H10OSn (cr)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -4.21 ± 0.1 | kcal/mol | RSC | Baldwin, Lappert, et al., 1972 |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A.,
Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin,
Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233
. [all data]
Pedley, Skinner, et al., 1957
Pedley, J.B.; Skinner, H.A.; Chernick, C.L.,
Thermochemistry of metallic alkyls. Part 8.?Tin tetramethyl, and hexamethyl distannane,
Trans. Faraday Soc., 1957, 53, 1612, https://doi.org/10.1039/tf9575301612
. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S.,
J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]
Notes
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- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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