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Al(Bu)3


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafliquid-372.5 ± 2.2kJ/molReviewMartinho SimõesLiquid tributylaluminum contains a very small molar fraction of monomer at 298 K, ca. 0.8% Smith, 1974, so that the "real" liquid should be described as [Al(Bu)3]2.
Quantity Value Units Method Reference Comment
Deltacliquid-9046.2 ± 1.3kJ/molCC-SBPawlenko, 1967Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C24H54Al2 (l) = 2C12H27Al (l)

By formula: C24H54Al2 (l) = 2C12H27Al (l)

Quantity Value Units Method Reference Comment
Deltar62.8 ± 0.6kJ/molEqSSmith, 1974 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Smith, 1974
Smith, M.B., J. Organometal. Chem., 1974, 70, 13. [all data]

Pawlenko, 1967
Pawlenko, S., Chem. Ber., 1967, 100, 3591. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]


Notes

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