Hg(Me)


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas47.9 ± 4.1kcal/molReviewMartinho SimõesThe enthalpy of formation relies on 22.1 ± 0.74 kcal/mol for the enthalpy of formation of Hg(Me)2(g).
Δfgas45.9 - 48.8kcal/molReviewMartinho SimõesThe enthalpy of formation limits rely on 22.1 ± 0.74 kcal/mol for the enthalpy of formation of Hg(Me)2(g).
Δfgas44.1 ± 1.7kcal/molReviewMartinho SimõesThe enthalpy of formation relies on 22.1 ± 0.74 kcal/mol for the enthalpy of formation of Hg(Me)2(g).

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Mercury, dimethyl- (g) = CH3Hg (g) + Methane (g)

By formula: C2H6Hg (g) = CH3Hg (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr57.2 ± 1.5kcal/molKinGJackson, 1989 
Δr59.0 - 61.9kcal/molN/ASmith and Patrick, 1983 
Δr61.0 ± 4.0kcal/molN/AMcMillen and Golden, 1982 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Jackson, 1989
Jackson, R.L., Chem. Phys. Lett., 1989, 163, 315. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]


Notes

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