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Ti(O-i-Pr)4


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-1507.9 ± 9.3kJ/molReviewMartinho SimõesSelected data. The enthalpy of formation relies on -1461.2 ± 3.1 kJ/mol for the enthalpy of formation of Ti(OEt)4(l)
Deltafgas-1486.8 ± 9.6kJ/molReviewMartinho Simões 
Deltafgas-1558. ± 17.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafliquid-1579.0 ± 3.9kJ/molReviewMartinho SimõesSelected data. The enthalpy of formation relies on -1461.2 ± 3.1 kJ/mol for the enthalpy of formation of Ti(OEt)4(l)
Deltafliquid-1557.9 ± 4.6kJ/molReviewMartinho Simões 
Deltafliquid-1629. ± 15.kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Deltacliquid-8109.8 ± 4.2kJ/molCC-SBGenchel, Volkova, et al., 1973Please also see Pedley and Rylance, 1977.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltavap71.1 ± 8.4kJ/molRSCBradley and Hillyer, 1966Please also see Pedley and Rylance, 1977.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Genchel, Volkova, et al., 1973
Genchel, V.G.; Volkova, E.A.; Aizatullova, R.M.; Shaulov, Yu.Kh., Zh. Fiz. Khim., 1973, 47, 1133. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Bradley and Hillyer, 1966
Bradley, D.C.; Hillyer, M.J., Thermochemistry of metal alkoxides. Part 2.?Heats of formation of some titanium alkoxides, Trans. Faraday Soc., 1966, 62, 2374, https://doi.org/10.1039/tf9666202374 . [all data]


Notes

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