LaCl3..LaCl4 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Cl4La- + Cl3La = Cl7La2-

By formula: Cl4La- + Cl3La = Cl7La2-

Quantity Value Units Method Reference Comment
Δr57.1 ± 9.8kcal/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr46.4 ± 8.2kcal/molTDAsButman, Kudin, et al., 1987gas phase; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Vorob'ev, et al., 2007
Kudin, L.S.; Vorob'ev, D.E.; Grishin, A.E., The Thermochemical Characteristics of the LnCl4- and Ln2Cl7- Negative Ions, Russ. J. Phys. Chem., 2007, 81, 2, 147, https://doi.org/10.1134/S003602440702001X . [all data]

Butman, Kudin, et al., 1987
Butman, M.F.; Kudin, L.S.; Burdukovskaya, G.G.; Krasnov, K.S.; Bozhko, N.V., Mass Spectrometric Determination of the Enthalpy of Formation of the Gaseous Ions LaCl4- and La2Cl7-, Russ. J. Phys. Chem., 1987, 61, 1518. [all data]


Notes

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