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N-pyrrolyl-CH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C5H6N- + Hydrogen cation = 1H-Pyrrole, 1-methyl-

By formula: C5H6N- + H+ = C5H7N

Quantity Value Units Method Reference Comment
Deltar1643. ± 13.kJ/molG+TSDePuy, Kass, et al., 1988gas phase; Anion of N-methyl-pyrrole. Between Me2NH, H2O.
Quantity Value Units Method Reference Comment
Deltar1615. ± 13.kJ/molIMRBDePuy, Kass, et al., 1988gas phase; Anion of N-methyl-pyrrole. Between Me2NH, H2O.

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C5H6N- + Hydrogen cation = 1H-Pyrrole, 1-methyl-

By formula: C5H6N- + H+ = C5H7N

Quantity Value Units Method Reference Comment
Deltar1643. ± 13.kJ/molG+TSDePuy, Kass, et al., 1988gas phase; Anion of N-methyl-pyrrole. Between Me2NH, H2O.
Quantity Value Units Method Reference Comment
Deltar1615. ± 13.kJ/molIMRBDePuy, Kass, et al., 1988gas phase; Anion of N-methyl-pyrrole. Between Me2NH, H2O.

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DePuy, Kass, et al., 1988
DePuy, C.H.; Kass, S.R.; Bean, G.P., Formation and Reactions of Heteroaromatic Anions in the Gas Phase, J. Org. Chem., 1988, 53, 19, 4427, https://doi.org/10.1021/jo00254a001 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References