MoF5..F anion
- Formula: F6Mo-
- Molecular weight: 209.95
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -1914. ± 20. | kJ/mol | Ther | Borshchevskii, Boltalina, et al., 1988 | value altered from reference due to conversion from electron convention to ion convention |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 3.82 ± 0.19 | R-A | Borshchevskii, Boltalina, et al., 1988 | value altered from reference due to conversion from electron convention to ion convention |
| 3.82038 | R-A | Borchevsky and Sidorov, 1985 | Fluoride Affinity: MoF5 > MoF4 by 10.1±0.3 kcal/mol; value altered from reference due to conversion from electron convention to ion convention |
| >5.10 ± 0.50 | NBIE | Compton, Reinhardt, et al., 1978 | |
| >4.50 ± 0.40 | NBIE | Mathur, Rothe, et al., 1977 |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Borshchevskii, Boltalina, et al., 1988
Borshchevskii, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Sidorov, L.N.,
Thermochemical Quantities for Gas Phase Iron, Uranium, and Molybdenum Fluorides, and Their Negative Ions.,
J. Chem. Thermodyn., 1988, 20, 5, 523, https://doi.org/10.1016/0021-9614(88)90080-8
. [all data]
Borchevsky and Sidorov, 1985
Borchevsky, A.Ya.; Sidorov, L.N.,
Ion-Molecule, Ion-Ion, and Molecule-Molecule Equilibria in the System Mo-U-Fe-F-O-e-,
Dokl. Akad. Nauk SSSR Ser. Khim., 1985, 285, 377. [all data]
Compton, Reinhardt, et al., 1978
Compton, R.N.; Reinhardt, P.W.; Cooper, C.D.,
Collisional ionization between fast alkali atoms and selected hexafluoride molecules,
J. Chem. Phys., 1978, 68, 2023. [all data]
Mathur, Rothe, et al., 1977
Mathur, B.P.; Rothe, R.W.; Reck, G.P.,
Ionization reactions of metal hexafluorides with alkali atoms and dimers,
J. Chem. Phys., 1977, 67, 377. [all data]
Notes
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- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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