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CH2=CHCH2O anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3H5O- + Hydrogen cation = 2-Propen-1-ol

By formula: C3H5O- + H+ = C3H6O

Quantity Value Units Method Reference Comment
Deltar373.5 ± 2.9kcal/molG+TSGraul, Schnute, et al., 1990gas phase
Deltar334. ± 12.kcal/molAcidKuhn, Fenzlaff, et al., 1988gas phase; From CH2=CHCH2OH, AP 0.9 eV; est. thermo = 2.5 eV
Deltar336.7 ± 2.0kcal/molD-EABouby, Compton, et al., 1968gas phase; EA probably 2 eV less
Quantity Value Units Method Reference Comment
Deltar366.6 ± 2.8kcal/molCIDCGraul, Schnute, et al., 1990gas phase
Deltar329.8 ± 2.1kcal/molH-TSBouby, Compton, et al., 1968gas phase; EA probably 2 eV less

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Graul, Schnute, et al., 1990
Graul, S.T.; Schnute, M.E.; Squires, R.R., Gas-Phase Acidities of Carboxylic Acids and Alcohols from Collision-Induced Dissociation of Dimer Cluster Ions, Int. J. Mass Spectrom. Ion Proc., 1990, 96, 2, 181, https://doi.org/10.1016/0168-1176(90)87028-F . [all data]

Kuhn, Fenzlaff, et al., 1988
Kuhn, A.; Fenzlaff, H.-P.; Illenberger, E., Formation and Dissociation of Negative Ion Resonances in Methanol and Allyl Alcohol, J. Chem. Phys., 1988, 88, 12, 7453, https://doi.org/10.1063/1.454309 . [all data]

Bouby, Compton, et al., 1968
Bouby, L.; Compton, R.N.; Souleyrol, A., Formation d'ions negatifs dans l'alcool allylique et l'acroleine., Comptes Rendues. Acad. Sc. Paris, 1968, 266, 1250. [all data]


Notes

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