Cr(CO)5 anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas<-861.90kJ/molR-EASallans, Lane, et al., 1985 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C5CrO5- + Bromine = C5BrCrO5-

By formula: C5CrO5- + Br = C5BrCrO5-

Quantity Value Units Method Reference Comment
Δr>295.4kJ/molIMRBJones, McDonald, et al., 1989gas phase

C5CrO5- + Iodine atom = C5CrIO5-

By formula: C5CrO5- + I = C5CrIO5-

Quantity Value Units Method Reference Comment
Δr>239.3kJ/molIMRBJones, McDonald, et al., 1989gas phase

C5CrO5- + Chlorine atom = C5ClCrO5-

By formula: C5CrO5- + Cl = C5ClCrO5-

Quantity Value Units Method Reference Comment
Δr>331.4kJ/molIMRBJones, McDonald, et al., 1989gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sallans, Lane, et al., 1985
Sallans, L.; Lane, K.R.; Squires, R.R.; Freiser, B.S., Generation and reactions of atomic metal anions in the gas phase. Determination of the heterolytic and homolytic bond energies of VH, VrH, FeH, CoH, and MoH, J. Am. Chem. Soc., 1985, 107, 4379. [all data]

Jones, McDonald, et al., 1989
Jones, M.T.; McDonald, R.N.; Schell, P.L.; Ali, M.H., Kinetics and Mechanism of Halogen Atom Transfer Reactions between Haloalkanes and Several 17-Electron Transition Metal Complex Negative Ions in the Gas Phase, J. Am. Chem. Soc., 1989, 111, 16, 5983, https://doi.org/10.1021/ja00198a001 . [all data]


Notes

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