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2-Nitro-«alpha»,«alpha»,«alpha»-trifluorotoluene anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-733. ± 10.kJ/molR-EAChowdhury and Kebarle, 1986«DELTA»Gea(423 K) = -29.9 kcal/mol; «DELTA»Sea (estimated) = -2 eu

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C7H4F3NO2- + Silicon tetrafluoride = C7H4F7NO2Si-

By formula: C7H4F3NO2- + F4Si = C7H4F7NO2Si-

Quantity Value Units Method Reference Comment
Deltar44.4 ± 2.5kJ/molIMREWilliamson, Knighton, et al., 2001gas phase; at 150 C

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C7H4F3NO2- + Silicon tetrafluoride = C7H4F7NO2Si-

By formula: C7H4F3NO2- + F4Si = C7H4F7NO2Si-

Quantity Value Units Method Reference Comment
Deltar44.4 ± 2.5kJ/molIMREWilliamson, Knighton, et al., 2001gas phase; at 150 C

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P., Electron affinities of di- and tetracyanoethylene and cyanobenzenes based on measurements of gas-phase electron transfer equilibria, J. Am. Chem. Soc., 1986, 108, 5453. [all data]

Williamson, Knighton, et al., 2001
Williamson, D.H.; Knighton, W.B.; Grimsrud, E.P., Lewis acid-base interactions of SiF4 with molecular anions formed by electron capture reactions, Int. J. Mass Spectrom., 2001, 206, 1-2, 53-61, https://doi.org/10.1016/S1387-3806(00)00388-2 . [all data]


Notes

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