CH2=CH2..F anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-52.9 ± 3.0kcal/molTherSullivan and Beauchamp, 1976Structure: Roy and McMahon, 1985

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sullivan and Beauchamp, 1976
Sullivan, S.A.; Beauchamp, J.L., Competition between proton transfer and elimination in the reactions of strong bases with fluoroethanes in the gas phase. Influence of base strength on reactivity, J. Am. Chem. Soc., 1976, 98, 1160. [all data]

Roy and McMahon, 1985
Roy, M.; McMahon, T.B., The Anomalous Gas Phase Acidity of Ethyl Fluoride. An ab initio Investigation of the Importance of Hydrogen Bonding between Fluoride and sp2 and sp C-H Bonds., Can. J. Chem., 1985, 63, 3, 708, https://doi.org/10.1139/v85-117 . [all data]


Notes

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