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CO3 radical anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-490. ± 50.kJ/molAVGN/AAverage of 6 out of 7 values; Individual data points

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CO3- + Water = CH2O4-

By formula: CO3- + H2O = CH2O4-

Quantity Value Units Method Reference Comment
Deltar58.99 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1979gas phase
Deltar48.1 ± 4.2kJ/molIMREFehsenfeld and Ferguson, 1974gas phase
Deltar<161.1kJ/molPDisSmith, Lee, et al., 1978gas phase
Quantity Value Units Method Reference Comment
Deltar27.6 ± 1.7kJ/molTDAsKeesee, Lee, et al., 1979gas phase
Deltar28.0 ± 1.7kJ/molIMREFehsenfeld and Ferguson, 1974gas phase

CO3- + Carbon dioxide = C2O5-

By formula: CO3- + CO2 = C2O5-

Quantity Value Units Method Reference Comment
Deltar24.7 ± 0.84kJ/molTDAsHiraoka and Yamabe, 1992gas phase
Deltar29.7 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar4.2 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1992gas phase
Deltar2.5 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase

CO3- + Acetic acid = C3H4O5-

By formula: CO3- + C2H4O2 = C3H4O5-

Quantity Value Units Method Reference Comment
Deltar47.28 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 1998gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Keesee, Lee, et al., 1979
Keesee, R.G.; Lee, N.; Castleman Jr., Properties of Clusters in the Gas Phase. 3. Hydration Complexes of CO3- and HCO3-, J. Am. Chem. Soc., 1979, 101, 10, 2599, https://doi.org/10.1021/ja00504a015 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Smith, Lee, et al., 1978
Smith, G.P.; Lee, L.C.; Cosby, P.C.; Peterson, J.R.; Moseley, J.T., Photodissociation and photodetachment of molecular negative ions. V. Atmospheric ions from 7000 to 8400 A), J. Chem. Phys., 1978, 68, 3818. [all data]

Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S., Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n, J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Viidanoja, Reiner, et al., 1998
Viidanoja, J.; Reiner, T.; Arnold, F., Laboratory Investigations of Negative Ion-Molecule Reactions of Formic and Acetic Acid., Int. J. Mass Spectrom., 1998, 181, 1-3, 31, https://doi.org/10.1016/S1387-3806(98)14151-9 . [all data]


Notes

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