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CO3 radical anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
>3.33999TherHunton, Hofmann, et al., 1985 
>3.07885LPESNovich, Engelking, et al., 1979 
3.10 ± 0.20CIDTTiernan and Wu, 1978 
3.25 ± 0.15PDVestal and Mauclaire, 1977 
>2.79954IMREDotan, Davidson, et al., 1977O3- + CO2 <=> CO3- + O2
2.69 ± 0.14PDHong, Woo, et al., 1977 
1.80 ± 0.20PDBurt, 1972actually photodissociation, Snodgrass, Roehl, et al., 1990

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunton, Hofmann, et al., 1985
Hunton, D.E.; Hofmann, M.; Lindeman, T.G.; Castleman, A.W., Photodissociation Dynamics of CO3-, J. Chem. Phys., 1985, 82, 1, 134, https://doi.org/10.1063/1.448786 . [all data]

Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C., Laser photoelectron, photodetachment, and photodestruction spectra of O3-, J. Chem. Phys., 1979, 70, 2652. [all data]

Tiernan and Wu, 1978
Tiernan, T.O.; Wu, R.L.C., Thermochemical Data for Molecular Negative Ions from Collisional Dissociation Thresholds, Adv. Mass Spectrom., 1978, 7A, 136. [all data]

Vestal and Mauclaire, 1977
Vestal, M.L.; Mauclaire, G.H., Photodissociaton of negative ions formed in CO2 and CO2/O2 Mixtures, J. Chem. Phys., 1977, 67, 3758. [all data]

Dotan, Davidson, et al., 1977
Dotan, I.; Davidson, J.A.; Streit, G.E.; Albritton, D.L.; Fehsenfeld, F.C., A study of the reaction O3- + CO2 = CO3- + O2 and its implication on the thermochemistry of CO3 and O3 and their negative ions, J. Chem. Phys., 1977, 67, 2874. [all data]

Hong, Woo, et al., 1977
Hong, S.P.; Woo, S.B.; Helmy, E.M., Photodetachment of thermally relaxed CO3-, Phys. Rev. A:, 1977, 15, 1563. [all data]

Burt, 1972
Burt, J.A., Photodetachment cross sections for CO3- and its first hydrate, J. Chem. Phys., 1972, 57, 4649. [all data]

Snodgrass, Roehl, et al., 1990
Snodgrass, J.T.; Roehl, C.M.; Vankoppen, P.A.M.; Palke, W.E.; Bowers, M.T., Photodissociation of CO3(-) - Product Kinetic Energy Measurements As a Probe of Excited State Potential Surfaces and Dissociation Dynamics, J. Chem. Phys., 1990, 92, 10, 5935, https://doi.org/10.1063/1.458363 . [all data]


Notes

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