Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

CO3 radical anion


Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-116. ± 10.kcal/molAVGN/AAverage of 6 out of 7 values; Individual data points

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CO3- + Water = CH2O4-

By formula: CO3- + H2O = CH2O4-

Quantity Value Units Method Reference Comment
Deltar14.10 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1979gas phase
Deltar11.5 ± 1.0kcal/molIMREFehsenfeld and Ferguson, 1974gas phase
Deltar<38.50kcal/molPDisSmith, Lee, et al., 1978gas phase
Quantity Value Units Method Reference Comment
Deltar6.60 ± 0.40kcal/molTDAsKeesee, Lee, et al., 1979gas phase
Deltar6.70 ± 0.40kcal/molIMREFehsenfeld and Ferguson, 1974gas phase

CO3- + Carbon dioxide = C2O5-

By formula: CO3- + CO2 = C2O5-

Quantity Value Units Method Reference Comment
Deltar5.90 ± 0.20kcal/molTDAsHiraoka and Yamabe, 1992gas phase
Deltar7.10 ± 0.10kcal/molTDAsKeesee, Lee, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar1.0 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase
Deltar0.60 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1980gas phase

CO3- + Acetic acid = C3H4O5-

By formula: CO3- + C2H4O2 = C3H4O5-

Quantity Value Units Method Reference Comment
Deltar11.30 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 1998gas phase

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
>3.33999TherHunton, Hofmann, et al., 1985 
>3.07885LPESNovich, Engelking, et al., 1979 
3.10 ± 0.20CIDTTiernan and Wu, 1978 
3.25 ± 0.15PDVestal and Mauclaire, 1977 
>2.79954IMREDotan, Davidson, et al., 1977O3- + CO2 <=> CO3- + O2
2.69 ± 0.14PDHong, Woo, et al., 1977 
1.80 ± 0.20PDBurt, 1972actually photodissociation, Snodgrass, Roehl, et al., 1990

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CO3- + Carbon dioxide = C2O5-

By formula: CO3- + CO2 = C2O5-

Quantity Value Units Method Reference Comment
Deltar5.90 ± 0.20kcal/molTDAsHiraoka and Yamabe, 1992gas phase
Deltar7.10 ± 0.10kcal/molTDAsKeesee, Lee, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar1.0 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase
Deltar0.60 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1980gas phase

CO3- + Acetic acid = C3H4O5-

By formula: CO3- + C2H4O2 = C3H4O5-

Quantity Value Units Method Reference Comment
Deltar11.30 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 1998gas phase

CO3- + Water = CH2O4-

By formula: CO3- + H2O = CH2O4-

Quantity Value Units Method Reference Comment
Deltar14.10 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1979gas phase
Deltar11.5 ± 1.0kcal/molIMREFehsenfeld and Ferguson, 1974gas phase
Deltar<38.50kcal/molPDisSmith, Lee, et al., 1978gas phase
Quantity Value Units Method Reference Comment
Deltar6.60 ± 0.40kcal/molTDAsKeesee, Lee, et al., 1979gas phase
Deltar6.70 ± 0.40kcal/molIMREFehsenfeld and Ferguson, 1974gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Keesee, Lee, et al., 1979
Keesee, R.G.; Lee, N.; Castleman Jr., Properties of Clusters in the Gas Phase. 3. Hydration Complexes of CO3- and HCO3-, J. Am. Chem. Soc., 1979, 101, 10, 2599, https://doi.org/10.1021/ja00504a015 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Smith, Lee, et al., 1978
Smith, G.P.; Lee, L.C.; Cosby, P.C.; Peterson, J.R.; Moseley, J.T., Photodissociation and photodetachment of molecular negative ions. V. Atmospheric ions from 7000 to 8400 A), J. Chem. Phys., 1978, 68, 3818. [all data]

Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S., Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n, J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Viidanoja, Reiner, et al., 1998
Viidanoja, J.; Reiner, T.; Arnold, F., Laboratory Investigations of Negative Ion-Molecule Reactions of Formic and Acetic Acid., Int. J. Mass Spectrom., 1998, 181, 1-3, 31, https://doi.org/10.1016/S1387-3806(98)14151-9 . [all data]

Hunton, Hofmann, et al., 1985
Hunton, D.E.; Hofmann, M.; Lindeman, T.G.; Castleman, A.W., Photodissociation Dynamics of CO3-, J. Chem. Phys., 1985, 82, 1, 134, https://doi.org/10.1063/1.448786 . [all data]

Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C., Laser photoelectron, photodetachment, and photodestruction spectra of O3-, J. Chem. Phys., 1979, 70, 2652. [all data]

Tiernan and Wu, 1978
Tiernan, T.O.; Wu, R.L.C., Thermochemical Data for Molecular Negative Ions from Collisional Dissociation Thresholds, Adv. Mass Spectrom., 1978, 7A, 136. [all data]

Vestal and Mauclaire, 1977
Vestal, M.L.; Mauclaire, G.H., Photodissociaton of negative ions formed in CO2 and CO2/O2 Mixtures, J. Chem. Phys., 1977, 67, 3758. [all data]

Dotan, Davidson, et al., 1977
Dotan, I.; Davidson, J.A.; Streit, G.E.; Albritton, D.L.; Fehsenfeld, F.C., A study of the reaction O3- + CO2 = CO3- + O2 and its implication on the thermochemistry of CO3 and O3 and their negative ions, J. Chem. Phys., 1977, 67, 2874. [all data]

Hong, Woo, et al., 1977
Hong, S.P.; Woo, S.B.; Helmy, E.M., Photodetachment of thermally relaxed CO3-, Phys. Rev. A:, 1977, 15, 1563. [all data]

Burt, 1972
Burt, J.A., Photodetachment cross sections for CO3- and its first hydrate, J. Chem. Phys., 1972, 57, 4649. [all data]

Snodgrass, Roehl, et al., 1990
Snodgrass, J.T.; Roehl, C.M.; Vankoppen, P.A.M.; Palke, W.E.; Bowers, M.T., Photodissociation of CO3(-) - Product Kinetic Energy Measurements As a Probe of Excited State Potential Surfaces and Dissociation Dynamics, J. Chem. Phys., 1990, 92, 10, 5935, https://doi.org/10.1063/1.458363 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References