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CO3 radical anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CO3- + Water = CH2O4-

By formula: CO3- + H2O = CH2O4-

Quantity Value Units Method Reference Comment
Deltar14.10 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1979gas phase
Deltar11.5 ± 1.0kcal/molIMREFehsenfeld and Ferguson, 1974gas phase
Deltar<38.50kcal/molPDisSmith, Lee, et al., 1978gas phase
Quantity Value Units Method Reference Comment
Deltar6.60 ± 0.40kcal/molTDAsKeesee, Lee, et al., 1979gas phase
Deltar6.70 ± 0.40kcal/molIMREFehsenfeld and Ferguson, 1974gas phase

CO3- + Carbon dioxide = C2O5-

By formula: CO3- + CO2 = C2O5-

Quantity Value Units Method Reference Comment
Deltar5.90 ± 0.20kcal/molTDAsHiraoka and Yamabe, 1992gas phase
Deltar7.10 ± 0.10kcal/molTDAsKeesee, Lee, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar1.0 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase
Deltar0.60 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1980gas phase

CO3- + Acetic acid = C3H4O5-

By formula: CO3- + C2H4O2 = C3H4O5-

Quantity Value Units Method Reference Comment
Deltar11.30 ± 0.20kcal/molIMREViidanoja, Reiner, et al., 1998gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Keesee, Lee, et al., 1979
Keesee, R.G.; Lee, N.; Castleman Jr., Properties of Clusters in the Gas Phase. 3. Hydration Complexes of CO3- and HCO3-, J. Am. Chem. Soc., 1979, 101, 10, 2599, https://doi.org/10.1021/ja00504a015 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Smith, Lee, et al., 1978
Smith, G.P.; Lee, L.C.; Cosby, P.C.; Peterson, J.R.; Moseley, J.T., Photodissociation and photodetachment of molecular negative ions. V. Atmospheric ions from 7000 to 8400 A), J. Chem. Phys., 1978, 68, 3818. [all data]

Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S., Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n, J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Viidanoja, Reiner, et al., 1998
Viidanoja, J.; Reiner, T.; Arnold, F., Laboratory Investigations of Negative Ion-Molecule Reactions of Formic and Acetic Acid., Int. J. Mass Spectrom., 1998, 181, 1-3, 31, https://doi.org/10.1016/S1387-3806(98)14151-9 . [all data]


Notes

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