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MeSiCH2 anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

C2H5Si- + Hydrogen cation = (CH3)2Si

By formula: C2H5Si- + H+ = C2H6Si

Quantity Value Units Method Reference Comment
Deltar1593. ± 21.kJ/molG+TSDamrauer, DePuy, et al., 1986gas phase; May have rearranged to 2-sila-allyl anion: G3MP2B3 calculations indicate an acidity of 361 kcal/mol
Quantity Value Units Method Reference Comment
Deltar1565. ± 21.kJ/molIMRBDamrauer, DePuy, et al., 1986gas phase; May have rearranged to 2-sila-allyl anion: G3MP2B3 calculations indicate an acidity of 361 kcal/mol

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, DePuy, et al., 1986
Damrauer, R.; DePuy, C.H.; Davidson, I.M.T.; Hughes, K.J., Gas phase ion chemistry of dimethylsilylene, Organometallics, 1986, 5, 2054. [all data]


Notes

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