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SnCl3 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Cl3Sn- + Hydrogen cation = HCl3Sn

By formula: Cl3Sn- + H+ = HCl3Sn

Quantity Value Units Method Reference Comment
Deltar288.80kcal/molN/ACheck, Faust, et al., 2001gas phase; NiCl3-; ; «DELTA»S(EA)=4.9
Quantity Value Units Method Reference Comment
Deltar280.40kcal/molN/ACheck, Faust, et al., 2001gas phase; NiCl3-; ; «DELTA»S(EA)=4.9

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.40 ± 0.20NBAELacmann, Maneira, et al., 1983From SnCl4
3.69 ± 0.50NBAEMathur, Rothe, et al., 1979From SnCl4
2.500 ± 0.010EIAEPabst, Margrave, et al., 1978From SnCl4
2.52999EIAEPabst, Perry, et al., 1977From SnCl4
4.14908N/ACheck, Faust, et al., 2001NiCl3-; ; «DELTA»S(EA)=4.9

Protonation reactions

Cl3Sn- + Hydrogen cation = HCl3Sn

By formula: Cl3Sn- + H+ = HCl3Sn

Quantity Value Units Method Reference Comment
Deltar288.80kcal/molN/ACheck, Faust, et al., 2001gas phase; NiCl3-; ; «DELTA»S(EA)=4.9
Quantity Value Units Method Reference Comment
Deltar280.40kcal/molN/ACheck, Faust, et al., 2001gas phase; NiCl3-; ; «DELTA»S(EA)=4.9

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Lacmann, Maneira, et al., 1983
Lacmann, K.; Maneira, M.J.P.; Moutinho, A.M.C.; Weigman, U., Total and Double Differential Cross Sections of Ion- Pair Formations in Collisions of K Atoms with SnCl4 and CCl4, J. Chem. Phys., 1983, 78, 1767. [all data]

Mathur, Rothe, et al., 1979
Mathur, E.P.; Rothe, E.W.; Reck, G.P., Negative ions from the reactions of alkalis with SnCl4, GeCl4, and TiCl4, Int. J. Mass Spectrom. Ion Phys., 1979, 31, 77. [all data]

Pabst, Margrave, et al., 1978
Pabst, R.E.; Margrave, J.L.; Franklin, J.L., Energy distribution in the products of ionic decomposition, Adv. Mass Spectrom., 1978, 7, 1217. [all data]

Pabst, Perry, et al., 1977
Pabst, R.E.; Perry, D.L.; Margrave, J.L.; Franklin, J.L., Electron impact studies of tin tetrahalides SnCl4, SnBr4 and SnI4, Int. J. Mass Spectrom. Ion Phys., 1977, 24, 323. [all data]


Notes

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