H2O..MeO anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-112.86 ± 0.54kcal/molTherMeot-ner and Sieck, 1986 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CH5O2- + 2Water = CH7O3-

By formula: CH5O2- + 2H2O = CH7O3-

Quantity Value Units Method Reference Comment
Δr19.2 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase
Quantity Value Units Method Reference Comment
Δr11.70 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CH5O2- + 2Water = CH7O3-

By formula: CH5O2- + 2H2O = CH7O3-

Quantity Value Units Method Reference Comment
Δr19.2 ± 1.0kcal/molTDAsMeot-Ner(Mautner), 1986gas phase
Quantity Value Units Method Reference Comment
Δr11.70 ± 0.50kcal/molTDAsMeot-Ner(Mautner), 1986gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-ner and Sieck, 1986
Meot-ner, M.; Sieck, L.W., Relative acidities of water and methanol, and the stabilities of the dimer adducts, J. Phys. Chem., 1986, 90, 6687. [all data]

Meot-Ner(Mautner), 1986
Meot-Ner(Mautner), M., Comparative Stabilities of Cationic and Anionic Hydrogen-Bonded Networks. Mixed Clusters of Water-Methanol, J. Am. Chem. Soc., 1986, 108, 20, 6189, https://doi.org/10.1021/ja00280a014 . [all data]


Notes

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