MeN(NO)CH2 anion
- Formula: C2H5N2O-
- Molecular weight: 73.0744
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
C2H5N2O- + =
By formula: C2H5N2O- + H+ = C2H6N2O
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1594. ± 8.8 | kJ/mol | G+TS | Ingemann and Nibbering, 1985 | gas phase; The experimental dHf(Me2NNO) { Korsunskii, Pepekin, et al., 1967} is incorrect: JEB, manuscript in preparation; value altered from reference due to change in acidity scale |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1564. ± 8.4 | kJ/mol | IMRE | Ingemann and Nibbering, 1985 | gas phase; The experimental dHf(Me2NNO) { Korsunskii, Pepekin, et al., 1967} is incorrect: JEB, manuscript in preparation; value altered from reference due to change in acidity scale |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ingemann and Nibbering, 1985
Ingemann, S.; Nibbering, N.M.M.,
Gas phase chemistry of dipole stabilized carbanions derived from N,N-dimethylthioformamide and N,N-dimethylnitrosamine,
Acta Chem. Scand., Ser. B, 1985, 39, 697. [all data]
Korsunskii, Pepekin, et al., 1967
Korsunskii, B.L.; Pepekin, V.I.; Lebedev, Yu.A.; Apin, A.Ya.,
Bull. Acad. Sci. USSR Div. Chem. Sci., 1967, 509. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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