Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

4-CO2Et-bicyclo[2.2.2]octene-CO2 anion


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.80 ± 0.16D-EATaft and Topsom, 1987value altered from reference due to change in acidity scale

Protonation reactions

C12H15O4- + Hydrogen cation = C12H16O4

By formula: C12H15O4- + H+ = C12H16O4

Quantity Value Units Method Reference Comment
Deltar338.9 ± 2.1kcal/molG+TSTaft and Topsom, 1987gas phase; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Deltar331.9 ± 2.0kcal/molIMRETaft and Topsom, 1987gas phase; value altered from reference due to change in acidity scale

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taft and Topsom, 1987
Taft, R.W.; Topsom, R.D., The Nature and Analysis of Substituent Effects, Prog. Phys. Org. Chem., 1987, 16, 1. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References