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bicyclo[2.2.2]octene-CO2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C9H11O2- + Hydrogen cation = Bicyclo[2.2.2]oct-2-ene-1-carboxylic acid

By formula: C9H11O2- + H+ = C9H12O2

Quantity Value Units Method Reference Comment
Deltar1432. ± 9.2kJ/molG+TSTaft and Topsom, 1987gas phase; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Deltar1403. ± 8.4kJ/molIMRETaft and Topsom, 1987gas phase; value altered from reference due to change in acidity scale

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.66 ± 0.16D-EATaft and Topsom, 1987value altered from reference due to change in acidity scale

Protonation reactions

C9H11O2- + Hydrogen cation = Bicyclo[2.2.2]oct-2-ene-1-carboxylic acid

By formula: C9H11O2- + H+ = C9H12O2

Quantity Value Units Method Reference Comment
Deltar1432. ± 9.2kJ/molG+TSTaft and Topsom, 1987gas phase; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Deltar1403. ± 8.4kJ/molIMRETaft and Topsom, 1987gas phase; value altered from reference due to change in acidity scale

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taft and Topsom, 1987
Taft, R.W.; Topsom, R.D., The Nature and Analysis of Substituent Effects, Prog. Phys. Org. Chem., 1987, 16, 1. [all data]


Notes

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